Conversion of 1-Octadenaol into Short Chain Alkenes and Alkanes Using Zsia Catalyst and Fluidized Bed Reactor at a Temperature of 400OC

Authors

  • Donatus Setyawan Purwo Handoko University of Jember
  • Triyono Gadjah Mada University

DOI:

https://doi.org/10.55927/fjst.v2i1.2611

Keywords:

1-Octadecene, Fluidized Bed Reactor, 1-Octadecanol

Abstract

Research has been carried out on the catalytic conversion of 1-octadecanol compounds into 1-octadecene alkanes at high temperatures (400oC) in a fluidized bed reactor. The research results obtained are as follows; Hydrogenation of 1-octadecanol was carried out in a fluidized bed reactor. The hydrogenation of 1-octadecanol was carried out in a fluidized bed reactor at a temperature of 400oC with 10 g of ZSiA catalyst and 10 g of pure 1-octadecanol reactant.The results of the study showed the following results: catalytic hydrogenation of 1-octadecanol with ZSiA catalyst at 400oC produced alkanes and alkenes in the chain length range up to C18 reaching 49.60% and the dominant compound produced was 1-octadecene with a relative concentration of up to 20 ,21 %.

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References

Anderson, J.R. and Boudart, M., 1981, Catalysis Science and Technology, First Edition, Springer Verlag, Berlin.

Augustine, R.L., 1996, Heterogeneous Catalysis for Chemist, Marcel Dekker Inc., New York.

Bartholomew, C. H. and Farrauto, R.J., 2006, Fundamentals of Industrial Catalytic Processes, 2nd edition, John Wiley and Sons Inc., New Jersey.

Belitz, H.D., and Grosch, W., 1999, Food Chemistry, 2nd edition, Springer-Verlag, Berlin.

Bell, A.T., 1987, Support and Metal Support Interaction in Catalyst Design, John Wiley & Sons, New York.

Boudart, M. and Bell A.T., 1987, Catalyst Design, 1st edition, A Wiley-Interscience Publication, New York.

Brands, D.S., Poels, E.K., Dimian, A.C. and Bliek, A., 2002, Solvent-Based Fatty Alcohol Synthesis Using Supercritical Butane : Flowsheet Analysis and Proses Design, J. Am. Chem, Vol 79 (1).

Boudreaux A., Kevin, 2013, General Chemistry, Departement of Chemistry, Angelo University, San Angelo, Texas.

Campbell, I. M., 1988, Catalysts at Surfaces, Chapman and Hall Ltd., New York.

Claus, J.H.J., Claus M., Jindrich H., Iver S. and Anna C., 2000, Mesoporous Zeolite Single Crystals, J. Am. Chem. Soc.:122, 7116-7117

Costas, S. T., 2000, Dealuminated H-Y Zeolite: Influence of The Degree and The Type of Dealumination Method on Structural and Acidic Characteristics of H-Y Zeolite, Ind. Eng. Chem:39, 307-319.

Demirbas, A. 2003. “Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey”. Energy Convers. Manage., 44, 2093-2109.

Demirbas, A., 2003, Fuel Conversional Aspect of Palm Oil and Sunflower, Energy Sources J., 5, 25, 154-167.

Demirbas, A., 2006, Biodiesel Production Via Non Catalytic SCF Method and Biodiesel Fuel Characteristics, Energy Convers. Manage., 47, 15-16, 2271 – 2282.

Dyer, A., 1988, An Introduction to Zeolite Molecular Sieves, John Wiley and Sons Ltd., Chichester.

Derouane, E.G., 1992, Zeolite Microporous Solids: Synthesis, Structure, and Reactivity, Kluwer Academic Publishers, London.

Dolbear, G.E, 1998, Hydrocracking: Reactions, Catalysts, and Processes,in Petroleum Chemistry and Refining, Taylor & Francis, Washington, D.C.

Fessenden, R.J. and Fessenden, J.S., 1986, Organic Chemistry, 3rd edition, Wadsworth, California.

Gasser, R.P.H., 1987, An Introduction to Chemisorption and Catalysis by Metal, Oxford Science Publication, Oxford.

Gates, B.C. 1979. Catalytic Chemistry, John Wiley and Sons Inc., New York.

Guisnet, M., 2002, “Coke” Molecules Trapped in The Micropores of Zeolites as Active Species in Hydrocarbon Transformations, J. Mol. Catal., 182-183, 367-382.

Hamdan, H., 1992, Introduction to Zeolites: Synthesis, Characterization, and Modification, Universiti Teknologi Malaysia, Penang.

Harber, J., 1991, Manual on Catalyst Characterization, Pure and Appl. Chem., 63, 9, 1227-1246.

Ketaren, 1986, Introduction to Food Oil and Fat Technology, University of Indonesia Press, Jakarta.

Khan, A. K., 2002, Research into Biodiesel, Kinetics & Catalyst Development, Department of Chemical Engineering, The University of Queensland, Brisbane.

Kloprogge T.J., Doung Loc V., and Ray L. Frost, 2005, A Review of The Synthesis and Characterization of Pillared Clays and Related Porous Material for Cracking of Vegetable Oil to Produce Biofuel, Env. Geo. J, 47, 7, 967-981.

Knothe, G., 2005, Dependence of Biodiesel Fuel Properties on the Structure of Fatty Acid Alkyl Esters, Fuel Process. Technol., 86, 1059– 1070.

Knothe, G., 2000, Monitoring a Progressing Transesterification Reaction by Fiber-Optic Near Infrared Spectroscopy with Correlation to 1H Nuclear Magnetic Resonance Spectroscopy, J. Am. Oil Chem. Soc., 77, 94, 489–493.

Knothe, G., Dunn, R. O., and Bagby, M. O., 1997, Biodiesel: The Use of Vegetable Oils and Their Derivatives as Alternative Diesel Fuels, Fuels and Chemicals from Biomass, ACS Symposium Series, V, 666.

Kunkeler P.J., 1998, Zeolite Beta: The Relationship between Calcination Procedure, Aluminum Configuration, and Lewis Acidity, J. Catal. 180, 234.

Laidler, K., J., 1950, Chemical Kinetics, 1st edition., McGraw-Hill Book Company, Inc., New York.

Lowell, S. and. Shields, J.E, 1984, Powder Surface Area and Porousity, 2nd edition, Chapman and Hall, New York.

Ma Fangrui and Hanna A. Milford, 1999, Biodiesel Production : a Review, Bioresource Technology, 70, 1-15.

Martinez, T.J., Diaz, C.M.J., Camblor, M.A., Fornes, V., Maesen, T.L.M. and Corma, A., 1999, The Catalytic Performance of 14-Membered Ring Zeolites, J. Catal., 182, 463-469.

May, C. Y., 2004, Transesterification of Palm Oil: Effect of Reaction Parameters, J. Oil Palm Res., 16, 2, 1-11.

Pachenkov, G. M., and Lebedev, V. P., 1976, Chemical Kinetic and Catalysis, 2nd edition., Mir Publishers, Moscow.

Page Le, J. F., Cosyns, J. and Courty, P., 1987, Applied Heterogenous Catalyst, edisi 1987, Imprimerie Nouvelle, Saint Jean de Braye, Paris.

Perry, R.H. dan Green, D.W., 1997, Perry’s Chemical Engineer’s Handbook, Mc.Graw-Hill Companies. Inc., New York.

Pioch, D. and Vaitilingom, G., 2005, Palm Oil and Derevatives: Fuels or Potensial Fuels?, Corps Gras, Lipides, 12, 2, 161-9.

Pramanik, T., and Tripathi, S., 2005, Biodiesel: Clean Fuel of the Future, Hydrocarbon Process., 2, 84, 49-54.

Rajeshwer, D., Sreenivasa Rao, G., Krishnamurthy, K., R., Padmavathi, G., Subrahmanyam, N. dan Jagdish, D. Rachh, 2006, Kinetics of Liquid – Phase Hydrogenation of Straight Chain C10 to C13 Di-Olefins Over Ni/Al2O3 Catalyst, International Journal of Chaemical Reactor Engineering, Vol. 4, Article A17

Ramesh, B.D., 2000, Hydrogenation of 1-alkenes Catalysed by Anchored Montmorillonite Palladium (II) Complexes : a Kinetic Study, Trans. Met. Chem, 25, 6, 639-643.

Rieke D. Ross, Deepak S. Thakur, Brian D. Roberts and Geoffrey T. White, 1997, Fatty Methyl Ester Hydrogenation to Fatty Alcohol Part II: Process Issues, JAOCS, Vol.74, no.4

Sang, O.Y., 2003, Biofuel Production From Catalytic Cracking of Palm Oil, Energy Sources J, 9, 25.

Santos, L.T., 2003, Nickel Activation for Hydrogenolysys Reaction on USY Zeolite, Catal. Lett. 92, 81.

Satterfield, C.N., 1980, Heterogenous Catalysis in Practices, McGraw-Hill Book Co., New York.

Sibilia, J.P., 1996, A Guide to Materials Characterization and Chemical Analysis, 2nd Edition. VCH Publishers, Inc., New York.

Smith, K., 1992, Solid Support and Catalyst in Organic Synthesis, Ellis Horwood PTR, Prentice Hall, London.

Treacy, M.M.J., and Higgins, J.B., 2001, Collection of Simulated XRD Powder Patternsfor Zeolite, Elsevier, Amsterdam.

Twaiq, F.A.A. and Bhatia, S., 2001, Catalytic Cracking of Palm Oil Over Zeolite Catalysts: Statistical Approach, IIUM Engineering Journal, Vol 2, No 1, Hal 13-21

Twaiq, F.A.A., Asmawati Noor M. Zabidi, Abdul Rahman Mohamed and Subhash Bhatia, 2003, Catalytic Conversion of Palm Oil Over Meso Porous Aluminosilicate MCM 41 for The Production of Liquid Hydrocarbon Fuel, Fuel Process Technol, 84, 1-3, 105 – 120.

Twaiq, F.A.A, Zabidi NAM dan Bhatia S., 1999, Catalytic Conversion of Palm Oil to Hydrocarbon: Performance of Various Zeolite Catalyst, Ind. Eng, Chem. Res. 38: 3230-3237.

Van Santen, R.A. and Kramer, G.J., 1995, Reactivity Theory of Zeolitic Bronsted Acidic Sites, J. Am. Chem. Soc : Chem. Rev, 95, 637-669.

West, A.R., 1984, Solid State Chemistry and It’s Application, John Willey & Sons, New York.

Wu Jing, 2005, Kinetics and Reactor Design, Department of Chemical Engineering, Hong Kong.

Yean Sang Ooi, Ridzuan Zakaria, Abdul Rahman Mohamed dan Subhash Bathia, 2004, Composite MCM-41/ZSM-5 as a Cracking Catalyst for Production of Liquid Fuel from Used Palm Oil, The 4th Annual Seminar of National Science Fellowship.

Yoon, C., 1997, Hydrogenation of 1,3-butadiena on Platinum Surfaces of Different Structures, Catal. Lett, 46, 37.

Zhang, W. and Smirniotis, P.G., 1999, Effect of Zeolite Structure and Acidity on the Product Selectivity and Reaction Mechanism for n-Octane Hydroisomerization and Hydrocracking, J. Catal., 182, 400-416.

Zhilong Yao, 2008, Research on Hydrogenation of FAME to Fatty Alcohol at Supercritical Conditions, Beijing Institute of Petrochemical Technology, Beijing.

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Published

2023-01-31

How to Cite

Handoko, D. S. P., & Triyono. (2023). Conversion of 1-Octadenaol into Short Chain Alkenes and Alkanes Using Zsia Catalyst and Fluidized Bed Reactor at a Temperature of 400OC. Formosa Journal of Science and Technology, 2(1), 349–362. https://doi.org/10.55927/fjst.v2i1.2611