Potensi Eceng Gondok (Eichhornia Crassiper) Sebagai Kalorimetri Kation dan Anion

Authors

  • Nurmala Sari Universitas Megarezky

Keywords:

water hyacinth, cation, anion, solvatochromic, ionochromic

Abstract

One of the compounds contained in water hyacinth is delhinidine 3-diglucosin. The compound is a compound that has the potential as a sensor for cations and anions because it has active groups, namely OH- and O. This study used the maceration method, then several tests were carried out, which obtained a water content of 10.24% and an ash content of 14.67%. The solvatochromic test on distilled water, methanol and acetone showed that there was a bathochromic shift and a hipsochromic shift. Meanwhile, the ionochromic qualitative test showed that the identification of cations was better than the anion test. The cation results showed that in distilled water (Yellow), water hyacinth could identify Cu2+ and Fe3+ (Green), in methanol solvent (Green) for Fe3+ metal (Yellow) while in acetone solvent (Green) it could identify Pb2+, and Fe3+ ( Yellow).

 

References

Alghiri, D., (2010). sintesis Turunan Chalcone dari Vanilin dan Potensi Penggunaannya sebagai Indikator Titrasi Asam Basa dan Sensor Anion. Tesis. Yogyakarta : Jurusan Kimia FMIPA UGM.

Anggaraini, S. (2012). Sintesis Senyawa 3-(4-hidroksi-3-metoksifenil)-1-fenil-2-propen-1-on dari Vanilin dan Uji Potensinya sebagai Larvasida untuk Aedes aegypti dan sensor anion. Skripsi. Yogyakarta: Jurusan Kimia FMIPA UGM.

Choi, Y., dan Kang, J., (2013). Chromogenic anion receptor based on 4-nitrophenylhydrazone. J. Incl Phenom Macrocycl Chem., 79, 95-102.

Fessenden, R. J., dan Fessenden, J. S., (1982). Kimia Organik, Diterjemahkan oleh Pudjaatmaka, A. H., Edisi Ketiga, Jilid 2. Jakarta : Erlangga.

Gerbono A, Djarijah AS. (2005). Kerajinan Eceng Gondok. Yogyakarta (ID): Kanisius.

Hanapi, U., (2010). Sintesis Turunan Senyawa Azo, Imina dan Azo-Imina dari Vanilin Sebagai Indikator Titrasi Asam-Basa. Tesis. Yogyakarta : Jurusan Kimia FMIPA UGM.

Hidayatullah A. (2011). Analisis Keuntungan Usaha Kerajinan Anyaman Eceng Gondok Di Kecamatan Amuntai Selatan Kabupaten Hulu 325.Sungai Utara. Ziraa’ah. 32 (3): 315

Huang, W., Li, Y., Lin, H., dan Lin, H., (2012). Colorimetric Recognition of Acetate Anions in Aqueous Solution Using Charge Neutral Azo Derivatives. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 86, 437-442.

Li, Y., Li, J., Lin, H., Shao, J., Cai, Z., dan Lin H., (2010). A Novel Colorimetric Receptor Responding AcO- Anions Based on an Azo Derivative in DMSO and DMSO/Water Solution. Journal of Luminescence, 130, 466-472.

Lin, C-I., Selvi., Fang, J-M., Chou, P-T., Lai< C-H., (2007). Pyreno[2,1-b]pyrrole and Bis(pyreno[2,1-b]pyrrole) as Selective Chemosensors of Fluoride Ion: A Mechanistic Study. J. Org. Chem., &2, 9, 3537-3542.

Millan, D., Dominuez, M., dan Rezende, M. C., 2008, Solvatochromic Hydrazone Anions Derived from Chalcones, Dyes and Pigments, 77, 441-445.

March, J., dan Smith, M. B., (2001). March’s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure. Fifth Edition, Jhon Wiley & Sons, Inc., New York.

Mirawati A. (2007). Perancangan buku bertema pemanfaatan eceng gondok beserta media promosinya. [Tesis]. Surabaya (ID): Petra Christian University.

Morrison, R.T., dan Boyd, R., N., (1973). Organic Chemistry, Second Edition, Prentice-Hall of India Private Limited. New Delhi.

Qiao, Y., Lin, H., Shao, J., dan Lin, H., (2009). A Highly Selective Naked-Aye Colorimetric Sensor for Acetate Ion Based on 1,10-phenanthroline-2,9-dicarboxyaldehyde-di-(p-sunstitutedphenyl-hydrazone). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 72, 378-381.

Reena, V., Suganya, S., dan Velmathi, S., (2013). Synthesis and Anion Binding Studies of Azo-Schiff Bases: Selective Colorimetric Fluoride and Acetate Ion Sensors. Journal of Fluorine Chemistry, 153, 89-95.

Reichardt, C., (1994). Solvatochromic Dyes as solvent Polarity Indicators. Chem. Rev., 94, 8, 2319-2358.

Rorong JA, Suryanto E. (2010). Analisis Fitokimia Eceng Gondok (Eichhornia crassipes) dan Efeknya sebagai Agen Photoreduksi Fe3+. 41.Chemistry Progress. 3(1): 33

Satheshkumar, A., Mossalamy, E. H., Manivannan, R., Parthiban, C., Al-Harbi, L. M., Kosa, S., dan Elango, K. P., (2014). Anion Induced Azo-Hydrazone Tautomerism for the Selective Colorimetric Sensing of Fluoride Ion. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 128, 798-805.

Shao, J., Lin, H., dan Lin H., (2009). A Novel Chromo- and Fluorogenic Dual Responding H2PO4- Receptor Based on an Azo Derivative. Dyes and Pigments, 80, 259-263.

Smith, M. B., dan March, J., (2007). March’s Advanced Organic Chemistry Reaction, Mechanisms, and Structure. A Jhon Wiley and Sons, Inc., United State America.

Stefhani CA, Mumu S, Pharmawati K. (2013). Fitoremediasi Phospat dengan Menggunakan Tumbuhan Eceng Gondok (Eichhornia crassipes) pada Limbah Cair Industri Kecil Pencucian Pakaian (Laundry). Reka Lingkungan Jurnal Institut Teknologi Nasional. 11.1(1): 1

Sykes, P., (1961). A Guidebook to Mechanism in Organic Chemistry. Longmans, Cambridge.

Xu, Z., Chen, X., Kim, H. N., dan Yoon, J., (2010). Sensor for the Optical Detection of Cyanide Ion. Chem. Soc. Rev., 39, 127-137.

Zhang, C., dan Suslick, K., S., (2005). A Colorimetric Sensor Array for Organics in Water. J. Am. Chem. Soc., 127, 11548-11549.

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Published

2022-04-23

How to Cite

Nurmala Sari. (2022). Potensi Eceng Gondok (Eichhornia Crassiper) Sebagai Kalorimetri Kation dan Anion. Jurnal Multidisiplin Madani, 2(3), 1269–1280. Retrieved from https://journal.formosapublisher.org/index.php/mudima/article/view/235

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