Effect of Acid Treatment on the Opening of Catalyst Pores

Donatus Setyawan Purwo Handoko

doi:10.55927/mudima.v3i3.2453

Authors

Donatus Setyawan Purwo Handoko Kimia Universitas Jember

DOI:

https://doi.org/10.55927/mudima.v3i3.2453

Keywords:

Zeolite, Calcination, Impregnation

Abstract

Research on the effect of acid treatment on the opening of the pore mouths on the surface of the zeolite catalyst has been carried out. The preparation of the zeolite catalyst was carried out through the processes of soaking, calcination, oxidation and reduction. Initially, the zeolite was soaked for 3 hours in distilled water, then drained and crushed until its size passed a 100 mesh sieve, followed by a calcination process with nitrogen for 5 hours. Then proceed with oxidation for 3 hours followed by a reduction process for 2 hours with hydrogen. Furthermore, the catalyst was impregnated with Ni from the salt {Ni.NO3.6(H2O)} After that the catalyst is stored and placed in a desiccator. Then an analysis of the catalyst obtained with AAS was carried out to determine the content of Na, Ca, Fe, Mg and K cations, and the content of Al and Si. Then continued with the analysis of acidity with gravimetric method and continued with analysis with the BET method to determine the specific surface area and pore size distribution. Furthermore, the catalyst is used in the catalytic cracking process at various temperatures

References

Augustine, R.L., 1996, Heterogeneous Catalysis for Chemist, Marcel Dekker Inc., New York.

Atkins, P.W., 1992, Physical Chemistry Volume II, fourth edition, Elangga, Jakarta.

Bartholomew, C. H. and Farrauto, R.J., 2006, Fundamentals of Industrial Catalytic Processes, 2nd edition, John Wiley and Sons Inc., New Jersey.

Belitz, H.D., and Grosch, W., 1999, Food Chemistry, 2nd edition, Springer-Verlag, Berlin. Brands, D.S., Poels, E.K.,

Dimian, A.C. and Bliek, A., 2002, Solvent-Based Fatty Alcohol Synthesis Using Supercritical Butane: Flowsheet Analysis and Process Design, J. Am.Chem, Vol 79 (1).

Campbell, I. M., 1988, Catalysts at Surfaces, Chapman and Hall Ltd., New York.

Costas, S. T., 2000, Dealuminated H-Y Zeolite: Influence of The Degree and The Type of

Dealumination Method on Structural and Acidic Characteristics of H-Y Zeolite, Ind. Eng. Chem:39, 307-319.

Demirbas, A. 2003. “Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey”. Energy Convers. Manage., 44, 2093-2109.

Demirbas, A., 2003, Fuel Conversional Aspect of Palm Oil and Sunflower, Energy Sources J., 5, 25, 154-167.

Demirbas, A., 2006, Biodiesel Production Via Non Catalytic SCF Method and Biodiesel Fuel Characteristics, Energy Convers. Manage., 47, 15-16, 2271 – 2282.

Demirbas, A., and Kara, H., 2006. New options for conversion of vegetable oils to alternative fuels, Energy Sources J., 28, 4-8, 619-626.

Dyer, A., 1988, An Introduction to Zeolite Molecular Sieves, John Wiley and Sons Ltd., Chichester. Derouane, E.G., 1992, Zeolite Microporous Solids: Synthesis, Structure, and Reactivity, Kluwer

Academic Publishers, London.

Dolbear, G.E, 1998, Hydrocracking: Reactions, Catalysts, and Processes,in Petroleum Chemistry and Refining, Taylor & Francis, Washington, D.C.

Fessenden, R.J. and Fessenden, J.S., 1986, Organic Chemistry, 3rd edition, Wadsworth, California.

Gasser, R.P.H., 1987, An Introduction to Chemisorption and Catalysis by Metal, Oxford Science Publication, Oxford.

Gates, B.C. 1979. Catalytic Chemistry, John Wiley and Sons Inc., New York.

Gaya, J.C.A., 2003, Biodiesel from Rape Seed Oil and Used Frying Oil in European Union, Copernicus Institute, Utrecht.

Groggins, P.H., 1952, Unit Processes in Organic Synthesis, Mc.Graw-Hill Book Company, Inc., New York.

Guisnet, M., 2002, “Coke” Molecules Trapped in The Micropores of Zeolites as Active Species in Hydrocarbon Transformations, J. Mol. Catal., 182-183, 367-382.

Hamdan, H., 1992, Introduction to Zeolites: Synthesis, Characterization, and Modification, Universiti Teknologi Malaysia, Penang.

Harber, J., 1991, Manual on Catalyst Characterization, Pure and Appl. Chem., 63, 9, 1227-1246.

Hughes, R., 1984, Deactivation of Catalyst, Academic Press Inc. Ltd., London.

Ketaren, 1986, Pengantar Teknologi Minyak dan Lemak Pangan, Universitas Indonesia Press, Jakarta.

Khan, A. K., 2002, Research into Biodiesel, Kinetics & Catalyst Development, Department of Chemical Engineering, The University of Queensland, Brisbane.

Kloprogge T.J., Doung Loc V., and Ray L. Frost, 2005, A Review of The Synthesis and Characterization of Pillared Clays and Related Porous Material for Cracking of Vegetable Oil to Produce Biofuel, Env. Geo. J, 47, 7, 967-981.

Knothe, G., 2005, Dependence of Biodiesel Fuel Properties on the Structure of Fatty Acid Alkyl Esters, Fuel Process. Technol., 86, 1059– 1070.

Knothe, G., 2000, Monitoring a Progressing Transesterification Reaction by Fiber-Optic Near Infrared Spectroscopy with Correlation to 1H Nuclear Magnetic Resonance Spectroscopy, J. Am. Oil Chem. Soc., 77, 94, 489–493.

Knothe, G., Dunn, R. O., and Bagby, M. O., 1997, Biodiesel: The Use of Vegetable Oils and Their Derivatives as Alternative Diesel Fuels, Fuels and Chemicals from Biomass, ACS Symposium Series, V, 666.

Kunkeler P.J., 1998, Zeolite Beta: The Relationship between Calcination Procedure, Aluminum Configuration, and Lewis Acidity, J. Catal. 180, 234.

Lowell, S. and. Shields, J.E, 1984, Powder Surface Area and Porousity, 2nd edition, Chapman and Hall, New York.

Martinez, T.J., Diaz, C.M.J., Camblor, M.A., Fornes, V., Maesen, T.L.M. and Corma, A., 1999,

The Catalytic Performance of 14-Membered Ring Zeolites, J. Catal., 182, 463-469.

Novirman Hendri, 2009, Pengaruh Temperatur pada Reaksi Hidrorengkah 1-oktadekena Menggunakan Katalis Ni/zeolit, Skripsi FMIPA UGM, Yogyakarta.

Pachenkov, G. M., and Lebedev, V. P., 1976, Chemical Kinetic and Catalysis, 2nd edition., Mir Publishers, Moscow.

Page Le, J. F., Cosyns, J. and Courty, P., 1987, Applied Heterogenous Catalyst, edisi 1987, Imprimerie Nouvelle, Saint Jean de Braye, Paris.

Perry, R.H. dan Green, D.W., 1997, Perry’s Chemical Engineer’s Handbook, Mc.Graw-Hill Companies. Inc., New York.

Pioch, D. and Vaitilingom, G., 2005, Palm Oil and Derevatives: Fuels or Potensial Fuels?, Corps Gras, Lipides, 12, 2, 161-9.

Rajeshwer, D., Sreenivasa Rao, G., Krishnamurthy, K., R., Padmavathi, G., Subrahmanyam, N. dan Jagdish, D. Rachh, 2006, Kinetics of Liquid – Phase Hydrogenation of Straight Chain C10 to C13 Di-Olefins Over Ni/Al2O3 Catalyst, International Journal of Chaemical Reactor Engineering, Vol. 4, Article A17

Ramesh, B.D., 2000, Hydrogenation of 1-alkenes Catalysed by Anchored Montmorillonite Palladium (II) Complexes : a Kinetic Study, Trans. Met. Chem, 25, 6, 639-643.

Sang, O.Y., 2003, Biofuel Production From Catalytic Cracking of Palm Oil, Energy Sources J, 9, 25.

Santos, L.T., 2003, Nickel Activation for Hydrogenolysys Reaction on USY Zeolite, Catal. Lett. 92, 81.

Satterfield, C.N., 1980, Heterogenous Catalysis in Practices, McGraw-Hill Book Co., New York.

Sibilia, J.P., 1996, A Guide to Materials Characterization and Chemical Analysis, 2nd Edition. VCH Publishers, Inc., New York.

Smith, K., 1992, Solid Support and Catalyst in Organic Synthesis, Ellis Horwood PTR, Prentice Hall, London.

Sutarti, M. dan Rachmawati, M., 1994, Zeolit: Tinjauan Literatur, Pusat dokumentasi dan dan Informasi LIPI, Jakarta.

Sykes and Peter, 1995, A Primer to Mechanism in Organic Chemistry, Addison Longman Ltd., Edinburgh.

Treacy, M.M.J., and Higgins, J.B., 2001, Collection of Simulated XRD Powder Patternsfor Zeolite, Elsevier, Amsterdam.

Twaiq F.A., Asmawati Noor M. Zabidi, Abdul Rahman Mohamed and Subhash Bhatia, 2003, Catalytic Conversion of Palm Oil Over Meso Porous Aluminosilicate MCM 41 for The Production of Liquid Hydrocarbon Fuel, Fuel Process Technol, 84, 1-3, 105 – 120.

Van Santen, R.A. and Kramer, G.J., 1995, Reactivity Theory of Zeolitic Bronsted Acidic Sites, J. Am. Chem. Soc : Chem. Rev, 95, 637-669.

West, A.R., 1984, Solid State Chemistry and It’s Application, John Willey & Sons, New York.

Wu Jing, 2005, Kinetics and Reactor Design, Department of Chemical Engineering, Hong Kong.

Yoon, C., 1997, Hydrogenation of 1,3-butadiena on Platinum Surfaces of Different Structures, Catal. Lett, 46, 37.

Yuan, W., Hansen, A. C., dan Zhang, Q., 2005, Vapor Pressure and Normal Boiling Point Predictions for Pure Methyl Esters and Biodiesel Fuels, Fuel, 84, 943-950.

Zhang, W. and Smirniotis, P.G., 1999, Effect of Zeolite Structure and Acidity on the Product Selectivity and Reaction Mechanism for n-Octane Hydroisomerization and Hydrocracking, J. Catal., 182, 400-416.