The Cracking of 1-Octadecanol Into Short Chain Alkane and Alkene Compounds
DOI:
https://doi.org/10.55927/fjsr.v4i1.13716Keywords:
Fluid Fixed Bed Reactor, 1-OktadecanolAbstract
Research has been carried out on the cracking mechanism of 1-octadecanol into short chain alkane and alkene compounds using a cracking technique using a Fluid Fixed Bed reactor, which is operated at temperatures between 450 oC to 500 oC for 30 minutes. The catalyst is positioned so that the feed vapor passes through a number of catalysts. The resulting product was analyzed using GC-MS. The results obtained are as follows. With the Ni/ZSiA catalyst, the catalytic hydrogenation of 1-octadecanol to 1-octadecene reached 20.21 percent, 5-octadecene reached 14.37 percent, and 9-octadecene reached 10.40 percent. The main product of catalytic hydrogenation is 1-octadecene. The results obtained at a hydrogen flow rate of 10 mL/minute and a temperature of 450 oC produce maximum alkane and alkene products < C12 (15.29%)
Downloads
References
Augustine, R.L., 1996, Heterogeneous Catalysis for Chemist, Marcel Dekker Inc., New York.
Bartholomew, C. H. and Farrauto, R.J., 2006, Fundamentals of Industrial Catalytic Processes, 2nd edition, John Wiley and Sons Inc., New Jersey.
Belitz, H.D., and Grosch, W., 1999, Food Chemistry, 2nd edition, Springer-Verlag, Berlin.
Bell, A.T., 1987, Support and Metal Support Interaction in Catalyst Design, John Wiley & Sons, New York.
Boudart, M. and Bell A.T., 1987, Catalyst Design, 1st edition, A Wiley-Interscience Publication, New York.
Brands, D.S., Poels, E.K., Dimian, A.C. and Bliek, A., 2002, Solvent-Based Fatty Alcohol Synthesis Using Supercritical Butane : Flowsheet Analysis and Proses Design, J. Am. Chem, Vol 79 (1).
Campbell, I. M., 1988, Catalysts at Surfaces, Chapman and Hall Ltd., New York.
Claus, J.H.J., Claus M., Jindrich H., Iver S. and Anna C., 2000, Mesoporous Zeolite Single Crystals, J. Am. Chem. Soc.:122, 7116-7117
Demirbas, A. 2003. “Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey”. Energy Convers. Manage., 44, 2093-2109.
Demirbas, A., 2003, Fuel Conversional Aspect of Palm Oil and Sunflower, Energy Sources J., 5, 25, 154-167.
Demirbas, A., 2006, Biodiesel Production Via Non Catalytic SCF Method and Biodiesel Fuel Characteristics, Energy Convers. Manage., 47, 15-16, 2271 – 2282.
Derouane, E.G., 1992, Zeolite Microporous Solids: Synthesis, Structure, and Reactivity, Kluwer Academic Publishers, London.
Dolbear, G.E, 1998, Hydrocracking: Reactions, Catalysts, and Processes,in Petroleum Chemistry and Refining, Taylor & Francis, Washington, D.C.
Dyer, A., 1988, An Introduction to Zeolite Molecular Sieves, John Wiley and Sons Ltd., Chichester.
Gasser, R.P.H., 1987, An Introduction to Chemisorption and Catalysis by Metal, Oxford Science Publication, Oxford.
Gates, B.C. 1979. Catalytic Chemistry, John Wiley and Sons Inc., New York.
Hamdan, H., 1992, Introduction to Zeolites: Synthesis, Characterization, and Modification, Universiti Teknologi Malaysia, Penang.
hang, W. and Smirniotis, P.G., 1999, Effect of Zeolite Structure and Acidity on the Product Selectivity and Reaction Mechanism for n-Octane Hydroisomerization and Hydrocracking, J. Catal., 182, 400-416.
Harber, J., 1991, Manual on Catalyst Characterization, Pure and Appl. Chem., 63, 9, 1227-1246.
Khan, A. K., 2002, Research into Biodiesel, Kinetics & Catalyst Development, Department of Chemical Engineering, The University of Queensland, Brisbane.
Knothe, G., 2000, Monitoring a Progressing Transesterification Reaction by Fiber-Optic Near Infrared Spectroscopy with Correlation to 1H Nuclear Magnetic Resonance Spectroscopy, J. Am. Oil Chem. Soc., 77, 94, 489–493.
Knothe, G., Dunn, R. O., and Bagby, M. O., 1997, Biodiesel: The Use of Vegetable Oils and Their Derivatives as Alternative Diesel Fuels, Fuels and Chemicals from Biomass, ACS Symposium Series, V, 666.
Lowell, S. and. Shields, J.E, 1984, Powder Surface Area and Porousity, 2nd edition, Chapman and Hall, New York.
May, C. Y., 2004, Transesterification of Palm Oil: Effect of Reaction Parameters, J. Oil Palm Res., 16, 2, 1-11.
nothe, G., 2005, Dependence of Biodiesel Fuel Properties on the Structure of Fatty Acid Alkyl Esters, Fuel Process. Technol., 86, 1059– 1070.
Page Le, J. F., Cosyns, J. and Courty, P., 1987, Applied Heterogenous Catalyst, edisi 1987, Imprimerie Nouvelle, Saint Jean de Braye, Paris.
Perry, R.H. dan Green, D.W., 1997, Perry’s Chemical Engineer’s Handbook, Mc.Graw-Hill Companies. Inc., New York.
Rajeshwer, D., Sreenivasa Rao, G., Krishnamurthy, K., R., Padmavathi, G., Subrahmanyam, N. dan Jagdish, D. Rachh, 2006, Kinetics of Liquid – Phase Hydrogenation of Straight Chain C10 to C13 Di-Olefins Over Ni/Al2O3 Catalyst, International Journal of Chaemical Reactor Engineering, Vol. 4, Article A17
Ramesh, B.D., 2000, Hydrogenation of 1-alkenes Catalysed by Anchored Montmorillonite Palladium (II) Complexes : a Kinetic Study, Trans. Met. Chem, 25, 6, 639-643.
Sang, O.Y., 2003, Biofuel Production From Catalytic Cracking of Palm Oil, Energy Sources J, 9, 25.
Santos, L.T., 2003, Nickel Activation for Hydrogenolysys Reaction on USY Zeolite, Catal. Lett. 92, 81.
Satterfield, C.N., 1980, Heterogenous Catalysis in Practices, McGraw-Hill Book Co., New York.
Sibilia, J.P., 1996, A Guide to Materials Characterization and Chemical Analysis, 2nd Edition. VCH Publishers, Inc., New York.
Treacy, M.M.J., and Higgins, J.B., 2001, Collection of Simulated XRD Powder Patternsfor Zeolite, Elsevier, Amsterdam.
Twaiq, F.A.A, Zabidi NAM dan Bhatia S., 1999, Catalytic Conversion of Palm Oil to Hydrocarbon: Performance of Various Zeolite Catalyst, Ind. Eng, Chem. Res. 38: 3230-3237.
Twaiq, F.A.A. and Bhatia, S., 2001, Catalytic Cracking of Palm Oil Over Zeolite Catalysts: Statistical Approach, IIUM Engineering Journal, Vol 2, No 1, Hal 13-21
Twaiq, F.A.A., Asmawati Noor M. Zabidi, Abdul Rahman Mohamed and Subhash Bhatia, 2003, Catalytic Conversion of Palm Oil Over Meso Porous Aluminosilicate MCM 41 for The Production of Liquid Hydrocarbon Fuel, Fuel Process Technol, 84, 1-3, 105 – 120.
Wu Jing, 2005, Kinetics and Reactor Design, Department of Chemical Engineering, Hong Kong.
Yean Sang Ooi, Ridzuan Zakaria, Abdul Rahman Mohamed dan Subhash Bathia, 2004, Composite MCM-41/ZSM-5 as a Cracking Catalyst for Production of Liquid Fuel from Used Palm Oil, The 4th Annual Seminar of National Science Fellowship.
Yoon, C., 1997, Hydrogenation of 1,3-butadiena on Platinum Surfaces of Different Structures, Catal. Lett, 46, 37.
Zhilong Yao, 2008, Research on Hydrogenation of FAME to Fatty Alcohol at Supercritical Conditions, Beijing Institute of Petrochemical Technology, Beijing.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Donatus Setyawan Purwo Handoko, Triyono

This work is licensed under a Creative Commons Attribution 4.0 International License.


























